(μ-Oxalato-κ4O1,O2:O1′,O2′)bis[bis(2,2′-bipyridine-κ2N,N′)cobalt(II)] μ6-oxido-dodeca-μ2-oxido-hexaoxido-hexatungstate(VI)

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Tris(2,2′-bipyridine)­cobalt(II) μ6-oxido-dodeca-μ2-oxido-hexa­oxidohexa­molydate(VI)

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(μ-Oxalato-κ4 O 1,O 2:O 1′,O 2′)bis­[bis­(2,2′-bipyridine-κ2 N,N′)cobalt(II)] μ6-oxido-dodeca-μ2-oxido-hexa­oxido-hexa­tungstate(VI)

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In the title complex, [(C(4)H(9))(4)N](2)[Mo(6)O(18)(C(9)H(9)NO(2))]·0.5C(4)H(10)O, the aryl-imido ligand is linked to an Mo atom of the Lindqvist-type polyoxidometalate anion by an Mo N bond of 1.726 (4) Å. The Mo N-C angles are 160.7 (5) and 167.6(5)° because of disorder affecting the aryl group, and is typical for the imido monodentate behaviour described in analogous hybrids. Light componen...

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Octa­kis(dimethyl sulfoxide-κO)cerium(III) μ6-oxido-dodeca-μ2-oxido-hexa­oxidohexa­molybdate(VI) dimethyl sulfoxide tetrasolvate

The title complex, [Ce(C(2)H(6)OS)(8)](2)[Mo(6)O(19)](3)·4C(2)H(6)OS, was obtained as a byproduct of the reaction of [(C(4)H(9))(4)N](2)[Mo(6)O(19)] with Ce(NO(3))(3)·6H(2)O and phthalic acid in dimethyl-sulfoxide solution. The asymmetric unit consists of a complex [Ce(C(2)H(6)OS)(8)](3+) cation, one and a half of the Lindqvist-type [Mo(6)O(19)](2-) polyanions and two dimethyl-sulfoxide solvent...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810023007